Temperature Jump Relaxation method is used to study: 

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DSSSB PGT Chemistry (Female) Official Paper (Held On: 06 Jul, 2018 Shift 1)
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  1. Fast reactions 
  2. Slow reactions 
  3. Moderate reactions 
  4. Substitution reactions 

Answer (Detailed Solution Below)

Option 1 : Fast reactions 
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CONCEPT:

Temperature Jump Relaxation Method

  • Temperature Jump Relaxation is a technique used in physical chemistry to study the kinetics of very fast chemical reactions, often in the microsecond or nanosecond timescale.
  • It involves a rapid increase in temperature (a "temperature jump") to perturb a chemical system that is initially at equilibrium.
  • The system responds to this perturbation by undergoing relaxation back to a new equilibrium state.
  • The relaxation process is monitored to determine the reaction rates and mechanism of fast reactions.

EXPLANATION:

  • Fast reactions occur on very short timescales, making it challenging to study them using conventional methods.
  • Temperature Jump Relaxation provides a way to create a sudden disturbance in the reaction system, enabling scientists to observe how the system responds dynamically.
  • The technique is particularly useful for studying reactions such as proton transfer, ion association/dissociation, and protein folding/unfolding, which occur on very short timescales.
  • Since the method focuses on the relaxation behavior of the system, it is specifically suited to fast reactions rather than slow or moderate ones.

Therefore, the correct answer is Option 1: Fast reactions.

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