The relationship between maturation and learning is

Development: Development describes the growth of humans throughout the lifespan, from conception to death. Development does not just involve the biological and physical aspects of growth, but also the cognitive and social aspects associated with development. 

Maturation and learning is the main principle of development

Maturation and learning: Maturation and learning are two intertwined processes. These are complementary to each other. Maturation facilitates learning. Maturation refers to the sequential characteristic of biological growth and development. The biological changes occur in sequential order and give children new abilities. Changes in the brain and nervous system help children to improve in thinking (cognitive) and motor (physical) skills. Also, children must mature to a certain point before they can progress to new skills (Readiness).

• For example, a four-month-old child cannot use language because the infant’s brain has not matured enough to allow the child to talk. By two years old, the brain has developed further and with help from others, the child will have the capacity to say and understand words.
• The child’s environment and the learning that occurs as a result of the child’s experiences largely determine whether the child will reach optimal development.
• A stimulating environment and varied experiences allow a child to develop to his or her potential.

Complimentary Relationship: Development is the result of the interaction of maturation and learning.​

• Maturity and learning both play their role simultaneously and therefore, it becomes difficult to determine which of the two is responsible for the behavior. 
• Maturation and learning are complementary processes.
• Maturation and learning are two processes through which development occurs.
• Maturation occurs due to the genetic raw material which an individual has.
• Learning or interactions with the environment in the form of doing various activities result in a behavior change.

Hence, we can conclude that the relationship between maturation and learning is complimentary.