Which of the following is diamagnetic?

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BPSC AE Paper 3 (General Studies) 14 Oct 2022 Official Paper
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  1. \(\rm O^+_2\)
  2. \(\rm O^{-2}_2\)
  3. \(\rm O^-_2\)
  4. O2

Answer (Detailed Solution Below)

Option 2 : \(\rm O^{-2}_2\)
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Detailed Solution

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The correct answer is O2-2.

Key Points

  • O2-2 is diamagnetic.
  • Diamagnetic substances are those which do not have any unpaired electrons and are not attracted to a magnetic field.
  • In the molecular orbital theory, the O2-2 ion has all its electrons paired, leading to its diamagnetic nature.
  • Other options such as O+2, O-2, and O2 have unpaired electrons, making them paramagnetic.

Additional Information

  • Diamagnetism is a property that arises from the pairing of electrons in an atom or molecule.
  • The presence of unpaired electrons in a species leads to paramagnetism, which is the opposite of diamagnetism.
  • Molecular orbital theory helps in understanding the magnetic properties of diatomic molecules by considering the filling of molecular orbitals with electrons.
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