'If a system A is in thermal equilibrium separately with B and C, then B and C are also in thermal equilibrium with each other.' This is 

  1. Zeroth law of thermodynamics
  2. First law of thermodynamics
  3. Second law of thermodynamics
  4. Third law of thermodynamics

Answer (Detailed Solution Below)

Option 1 : Zeroth law of thermodynamics
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Explanation:

There are 4 laws to thermodynamics:

Zeroth Law of thermodynamics: It states that, When a body ‘A’ is in thermal equilibrium with a body B, and also separately with a body C, then B and C will be in thermal equilibrium with each other. This is the basis of temperature measurement

  • In other words, If two thermodynamic systems are each in thermal equilibrium with a third, then they are in thermal equilibrium with each other.

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Additional Information

First law of thermodynamics  Energy can neither be created nor destroyed. It can only change forms. In any process, the total energy of the universe remains the same.

For a thermodynamic cycle, the net heat supplied to the system equals the net work done by the system.

δQ = ΔU + δW

Second law of thermodynamics – The entropy of an isolated system not in equilibrium will tend to increase over time, approaching a maximum value at equilibrium.

ΔS = ΔQ/T

⇒ ΔS⋅T = ΔQ

In differential form, dQ = Tds

ΔSTotal = ΔSSystem + ΔSsurrounding

The second law of thermodynamics introduces the concept of entropy.

Second Law of Thermodynamics:

  1. Clausius statement: It is impossible for a self-acting machine to transfer heat from a colder body to a hotter one without the aid of an external agency
  2. Kelvin-Planck’s statement: It is impossible to design an engine that extracts heat and fully utilizes into work without producing any other effect.

Third law of thermodynamics – As the temperature approaches absolute zero, the entropy of a system approaches a constant minimum.

ΔST = 0K = 0
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