Question
Download Solution PDF
on dehydration gives
Answer (Detailed Solution Below)
Option 2 : 
Free Tests
View all Free tests >
UP TGT Hindi FT 1
9.8 K Users
125 Questions
500 Marks
120 Mins
Detailed Solution
Download Solution PDFConcept:
Dehydration reaction of alcohols:
- Alcohols when heated at high temperatures in presence of conc acids, undergo dehydration.
- They lose a molecule of water and form alkenes.
- The reaction proceeds via a carbocationic intermediate.
- The ease of dehydration follows the order tertiary>secondary>primary.
- There is a formation of unexpected products because the rearrangement of carbocations takes place in the reaction.
- Carbocationic rearrangement takes place whenever there is a possibility of a more stable intermediate to be formed by rearrangement.
- More stable carbonation gives a more saturated alkene as the product.
Explanation:
- In the first step, the nucleophilic oxygen of the OH group of alcohol takes up a proton from the acid.
- In the next step elimination of water molecule takes place and gives the carbocationic intermediate.
- In the third step Rearrangement of this intermediate takes place to give a more stable carbocation.
- Finally, elimination of proton occurs giving more substituted alkenes.
- The mechanism is:
Hence, on dehydration is
.
Last updated on May 6, 2025
-> The UP TGT Exam for Advt. No. 01/2022 will be held on 21st & 22nd July 2025.
-> The UP TGT Notification (2022) was released for 3539 vacancies.
-> The UP TGT 2025 Notification is expected to be released soon. Over 38000 vacancies are expected to be announced for the recruitment of Teachers in Uttar Pradesh.
-> Prepare for the exam using UP TGT Previous Year Papers.