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Option 2 : F1 Utkarsha 23.11.20 Pallavi D15
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Concept:

Dehydration reaction of alcohols:

  • Alcohols when heated at high temperatures in presence of conc acids, undergo dehydration.
  • They lose a molecule of water and form alkenes.
  • The reaction proceeds via a carbocationic intermediate.
  • The ease of dehydration follows the order tertiary>secondary>primary.
  • There is a formation of unexpected products because the rearrangement of carbocations takes place in the reaction.
  • Carbocationic rearrangement takes place whenever there is a possibility of a more stable intermediate to be formed by rearrangement.
  • More stable carbonation gives a more saturated alkene as the product.

Explanation:

  • In the first step, the nucleophilic oxygen of the OH group of alcohol takes up a proton from the acid.
  • In the next step elimination of water molecule takes place and gives the carbocationic intermediate. 
  • In the third step Rearrangement of this intermediate takes place to give a more stable carbocation.
  • Finally, elimination of proton occurs giving more substituted alkenes.
  • The mechanism is:

D1 Puja Madhuri 20.05.2021 D1

Hence, F1 Utkarsha 23.11.20 Pallavi D11 on dehydration is F1 Utkarsha 23.11.20 Pallavi D15.

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