Question
Download Solution PDFThe ratio of specific rate constants at two different temperatures, separated by 10 °C, is called as:
Answer (Detailed Solution Below)
Detailed Solution
Download Solution PDFCONCEPT:
Temperature Coefficient
- The temperature coefficient is the ratio of specific rate constants (k) at two different temperatures separated by 10°C.
- This is a measure of how the rate of a chemical reaction changes with temperature.
- It is based on the principle that reaction rates generally increase with temperature due to increased molecular collisions and the energy required to overcome the activation barrier.
- Mathematically, the temperature coefficient is expressed as:
Temperature Coefficient = k2/k1
Where k2 and k1 are the rate constants at two temperatures separated by 10°C.
EXPLANATION:
- The ratio of specific rate constants at two different temperatures is not related to activity coefficient, activation energy, or threshold energy.
- Activity coefficient measures the effective concentration of a species in a solution and is unrelated to temperature changes.
- Activation energy refers to the minimum energy required to start a reaction, while threshold energy is the minimum energy required for molecular collisions to result in a reaction.
- The specific term "temperature coefficient" directly relates to the change in reaction rate constants with temperature, making it the correct answer.
Therefore, the correct answer is option 4: Temperature Coefficient.
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