EDTA is

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  1. Unidentate ligand
  2. Bidentate ligand
  3. Tridentate ligand
  4. Hexadentate ligand

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Option 4 : Hexadentate ligand
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CONCEPT:

Ligands and Denticity

  • A ligand is an ion or molecule that binds to a central metal atom to form a coordination complex.
  • The number of donor atoms of a ligand that bind to the central metal atom is called the denticity of the ligand.
  • Ligands can be classified based on their denticity:
    • Unidentate ligand: Binds through a single donor atom.
    • Bidentate ligand: Binds through two donor atoms.
    • Tridentate ligand: Binds through three donor atoms.
    • Hexadentate ligand: Binds through six donor atoms.

EXPLANATION:

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  • EDTA (Ethylenediaminetetraacetic acid) is a common ligand used in coordination chemistry.
  • EDTA has six donor atoms (four oxygen atoms from carboxyl groups and two nitrogen atoms from amine groups) that can simultaneously bind to a central metal atom.
  • This makes EDTA a hexadentate ligand because it can form six bonds with the central metal atom.

Therefore, EDTA is a hexadentate ligand.

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