Which of the following is a soapy liquid with large molecular size of the order of 10–9 m?

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  1. Palmitic acid
  2. Stearic acid
  3. Lauric acid
  4. Oleic acid

Answer (Detailed Solution Below)

Option 4 : Oleic acid
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The correct answer is Oleic acid.

Key Points

  • Oleic acid is a monounsaturated fatty acid with a large molecular size, approximately 10-9 meters, enabling it to form a soapy liquid.
  • It is commonly found in vegetable oils such as olive oil and is known for its amphiphilic nature, meaning it has both hydrophilic and hydrophobic properties.
  • The amphiphilic structure of oleic acid allows it to act as a surfactant, reducing surface tension and forming micelles in water.
  • Oleic acid is widely used in soaps, detergents, and emulsifiers due to its ability to stabilize mixtures of oil and water.
  • Its molecular size and properties make it suitable for applications in industries like cosmetics, pharmaceuticals, and food production.

Additional Information

  • Fatty Acids:
    • Fatty acids are carboxylic acids with long hydrocarbon chains that may be saturated or unsaturated.
    • Saturated fatty acids like palmitic acid have no double bonds, while unsaturated fatty acids like oleic acid have one or more double bonds.
    • The molecular size and structure of fatty acids influence their physical and chemical properties.
  • Surfactants:
    • Surfactants are compounds that lower the surface tension between two substances, such as oil and water.
    • They are commonly used in cleaning products, emulsifiers, and foaming agents.
    • Oleic acid acts as a surfactant due to its amphiphilic nature.
  • Micelles:
    • Micelles are spherical structures formed when amphiphilic molecules like oleic acid aggregate in water.
    • They play a key role in the cleansing properties of soaps and detergents.
    • Micelles trap oil and dirt, making them water-soluble for easy removal during washing.
  • Applications of Oleic Acid:
    • It is widely used in the cosmetic industry for formulations like moisturizers and lotions.
    • In the pharmaceutical industry, oleic acid is used as a solvent and emulsifier in drug formulations.
    • It is also utilized in the food industry as a component of cooking oils and flavoring agents.
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