Strongest ligand in spectrochemical series is -

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HPSC Assistant Professor 2018 Chemistry (Official Paper)
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  1. CN-
  2. CI-
  3. Br-
  4. I-

Answer (Detailed Solution Below)

Option 1 : CN-
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Detailed Solution

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CONCEPT:

Spectrochemical Series

  • The spectrochemical series is a list of ligands ordered by the field strength they exert on the central metal ion.
  • Ligands that exert a stronger field cause a larger splitting of d-orbitals in the metal ion, leading to greater separation between energy levels.
  • This series helps predict the color and properties of coordination complexes based on their ligands.

EXPLANATION:

  • In the spectrochemical series, ligands are arranged in order of increasing field strength. Some common ligands in order are:
    • \(I^- < Br^- < Cl^- < F^- < OH^- < H_2O < NH_3 < en < NO_2^- < CN^- < CO\)
  • Among the provided options ( \(CN^- , Cl^- , Br^- , I^- \)):
    • CN- (cyano) is the strongest ligand, exerting the greatest field strength.

The correct answer is: 1) CN^−

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