Question
Download Solution PDFMolar specific heat capacity of a substance is _________.
Answer (Detailed Solution Below)
Detailed Solution
Download Solution PDFExplanation:
Specific heat capacity:
- It is the amount of heat required to raise the temperature of a unit mass of a substance by one degree Celcius.
- Specific heat capacity (c) is related to the heat (Q) and temperature (T) as follows
- ΔQ = mc ΔT........(1)
- The SI unit of specific heat capacity is J kg-1 K-1
Molar Specific Heat or Molar Heat Capacity
- The molar heat capacity of a substance is defined as the amount of heat required to raise the temperature of one gram mole of the substance by one degree Celsius.
- Its unit is cal.mol-1°C-1 or J.mol-1K-1
- The molar-specific heat of a substance is generally represented by C.
- If the specific heat of a substance is c and its gram molar mass is M, then
- C = Mc.....(2)
- From equation 1 and 2
- \(Δ Q=\frac{C}{M}m Δ T\)
- ΔQ = μCΔT
- where, μ = m/M
- \(C=\frac{1}{µ} \frac{ΔQ}{ΔT}\)
-
where, µ is the number of moles.
- Molar-specific heat of gas is of two types. This is because the amount of heat required to raise the temperature of one mole of a gas is different when:
- heat is supplied at constant pressure Cp and
- when heat is supplied at constant volume Cv
(a) Molar specific heat of a gas at constant pressures Cp
- The amount of heat energy required to raise the temperature of one mole of a gas by 1°C constant pressure is called molar specific heat of a gas at constant pressure:
(b) Molar specific heat of a gas at constant volume Cv
- The amount of heat energy required to raise the temperature of one mole of a gas by 1°C at constant volume is called molar specific heat of a gas at constant volume.
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