The electrolyte used in mercury cell is 

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AIIMS BSc NURSING 2024 Memory-Based Paper
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  1. Moist paste of NH4Cl and ZnCl
  2. 38% solution of H2SO4
  3. Paste of KOH and ZnO
  4. Paste of MgCl2, and HgO

Answer (Detailed Solution Below)

Option 3 : Paste of KOH and ZnO
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AIIMS BSc NURSING 2024 Memory-Based Paper
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Detailed Solution

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CONCEPT:

Mercury Cell

  • The mercury cell, also known as a mercury battery, is a non-rechargeable electrochemical battery.
  • It consists of a zinc anode, a mercury oxide cathode, and an electrolyte that is typically a paste of potassium hydroxide (KOH) and zinc oxide (ZnO).
  • These cells are known for their stable output voltage and long shelf life.

EXPLANATION:

  • The electrolyte used in a mercury cell is a paste of KOH and ZnO.
  • Other options are incorrect:
    • Option 1: A moist paste of NH4Cl and ZnCl2 is used in dry cells, not mercury cells.
    • Option 2: A 38% solution of H2SO4 is typically used in lead-acid batteries, not mercury cells.
    • Option 4: A paste of MgCl2 and HgO is not a known electrolyte for mercury cells.

Therefore, the correct answer is option 3: Paste of KOH and ZnO.

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