The term (h-T.S) in deriving the maximum work done for a steady flow system is known as

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HPCL Engineer Mechanical 12 Aug 2021 Official Paper (Shift 1)
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  1. Van-der function
  2. Rankine function
  3. Helmholtz function
  4. Gibbs function

Answer (Detailed Solution Below)

Option 4 : Gibbs function
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Explanation:

Gibbs Function:

  • Also known as the Gibbs free energy, Gibbs energy, or Free Enthalpy, is a quantity that is used to measure the maximum amount of work done in a thermodynamic system when the temperature and pressure are kept constant.
  • Gibb's free energy is denoted by the symbol ‘G’. Its value is usually expressed in Joules or Kilojoules.
  • Gibb's free energy can be defined as the maximum amount of work that can be extracted from a closed system.

Gibbs Free Energy Equation:

G = H – TS

Where, G = Gibbs free energy, H = enthalpy, T = temperature, S = entropy

⇒ G = U + PV – TS

Where, U = Internal energy, P = Pressure, V = Volume, T = Temperature, S = Entropy

Additional Information

ΔG = ΔH – TΔS 

This equation is called the Gibbs Helmholtz equation.

ΔG > 0; the reaction is non-spontaneous and Endergonic.

ΔG < 0; the reaction is spontaneous and Exergonic.

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