The v-shaped graph represents conductometric titration of: 

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DSSSB PGT Chemistry (Female) Official Paper (Held On: 06 Jul, 2018 Shift 1)
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  1. Strong acid vs weak base  
  2. Strong acid vs strong base 
  3. Weak acid vs weak base 
  4. Strong acid & weak acid vs weak base 

Answer (Detailed Solution Below)

Option 2 : Strong acid vs strong base 
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CONCEPT:

Conductometric Titration

  • Conductometric titration involves the measurement of electrical conductivity during a titration process to monitor the progress of the reaction.
  • The conductivity of the solution changes based on the nature of the ions present during the titration.
  • In the case of a strong acid vs strong base titration, the reaction leads to the formation of neutral water molecules, which results in a distinct "V-shaped" graph.

EXPLANATION:
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  • In a titration between a strong acid and a strong base:
    • Initially, the solution contains excess H+ ions from the strong acid, which contribute to high conductivity.
    • As the strong base is added, OH- ions react with H+ ions to form neutral water molecules (H2O), reducing the number of free ions and decreasing conductivity.
    • At the equivalence point, all H+ ions are neutralized, and the conductivity reaches a minimum.
    • Beyond the equivalence point, excess OH- ions from the strong base increase the conductivity, resulting in the "V-shaped" graph.
  • This characteristic "V-shaped" graph is specific to the titration of a strong acid with a strong base.

Therefore, the correct answer is Strong acid vs strong base.

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