Which of the following is not the characteristic of physisorption?

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CUET Chemistry 10th Aug 2022 Official Paper
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  1. It arises because of vander Waals forces.
  2. It is not specific in nature.
  3. Enthalpy of adsorption is high.
  4. It results into multi molecular layers on adsorbent surface under high pressure.

Answer (Detailed Solution Below)

Option 3 : Enthalpy of adsorption is high.
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Explanation:

Enthalpy of adsorption is high - is NOT a characteristic of physisorption.

  • Adsorption - The accumulation of molecular species at the surface rather than in the bulk of a solid or liquid.
  • Two types of adsorption of gases on solids - Physisorption (physical adsorption) and Chemisorption (chemical adsorption).
  • Physisorption (physical adsorption) - When the accumulation of gas on the surface of a solid occurs on account of weak van der Waals' forces.
  • Chemisorption (chemical adsorption) - When the gas molecules or atoms are held to the solid surface by chemical bonds.

In physisorption, enthalpy of adsorption is low ( 20- 40 kJ mol–1 ) whereas in the case of chemisorption enthalpy of adsorption is high (80 – 240 kJmol–1

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